So for electrical fires, they use carbon dioxide to smother the fire and sodium bicarbonate to aid in putting it out, along with class c fire extinguishers. Class c are just carbon dioxide.
For chemical fires, carbon dioxide extinguishers are also used. They can use extinguishers with bromochlorodifluoromethane, aka Halon 1211, (which I guess could be a pfas chemical, but I don’t find anything either way).