It depends. Is this energy the same energy that is already being burned?
Looking at an extremely simple example: Solar powered calculators (the real ones). They harness light from the light bulbs in a room which would be otherwise dark. The only time they are harnessing that power, is when the light is on. They add no extra draw to the light, they are 100% passive. The only time you’d really have to take into consideration how green that power is (explicitly for the calculator) is if you are turning on that light explicitly to power the calculator.
If the tech being talked about is just harnessing the “junk energy” of the vehicles in their normal operation, this would be 100% green energy. If it is adding a load, it is 100% dirty when powered by an ICE. If it’s somewhere in the middle… I hope you get my point.
You’re also ignoring the fact that not all vehicles are ICE.