It looks like regular PSUs are isolated from the mains ground with a transformer. That means that two PSUs’ DC grounds will not be connected. That will likely cause problems for you, as they’ll have to back flow current in places that do NOT expect back flow current to account for the voltage differences between the two ground potentials. Hence it might damage the GPU which is going be the mediator between these two PSUs - and maybe the mobo if everything goes to shit.
Now I am not saying this will be safe, but you may avoid that issue by tying the grounds of the two PSUs together. You still have the issue where if, say, PSU1’s 12V voltage plane meets PSU2’s 12V voltage plane and they’re inevitably not the same exact voltage, you’ll have back flowing current again which is bad because again nothing is designed for that situation. Kind of like if you pair lithium batteries in parallel that aren’t matched, the higher voltage one will back charge the other and they’ll explode.