Clearly you can address more bytes than your data bus width. But then why all the “hacks” on 32-bit architectures? Like the 36-bit address bus via memory mapping on SPARCv8 instead of using paired index registers ( or ARMv7 width LPAE). From a perfomance perspective using an address width that is not the native register width/ internal data bus width is an issue. For a significant subset of operations multiple instructions are required instead of one.
Also is your comment about turing completeness to be taken seriously? We are talking about performance and practicality. Go ahead and crunch on some 64-bit floats using purely 8-bit arithmetic operations (or even using vector registers). Of course you can, but the point is that a suitable word size is more effective for certain computational tasks. For operations that are done frequently, they should ideally be done at native data-bus width. Vectored operations will also cost performance.