Since both drives are SSDs there’s nothing really stopping you from using BTRFS. You are correct that the features for BTRFS are better for the long term health of your SSDs and if you feel comfortable with it then you should 100% use it. That being said with todays SSDs the life span extending features of BTRFS, F2FS, etc are going to be minimal at best. So don’t stress too much over running it or not. Just use whatever you’re most comfortable with.