Personally I would take this opportunity to segregate /home and / on two distinct SSDs. You can upgrade them separately in the future, optimize each of them for different purposes, you can fuff around with system partitions and trying new distros and whatnot without touching home etc.
There’s nothing outstanding to gain from RAID0 if you don’t need the increase in speed. You could make an argument for RAID1 but unless you actually need 100% availability, again, not worth the complications. Take frequent backups (preferably incremental) and that’s it.