in AC, which is what home electricity uses, the polarity is constantly switching, from + , then - , then + , and so on, 50 or 60 times a second depending on where you live. This means that, unlike batteries, it’s symmetrical, and you can just splice the cables and attach two male plugs together and they will work regardless, even if you somehow attach the neutral to live and live to neutral, in fact in many countries you can actually buy just the plug without the cable and then you can assemble it yourself in whatever way you please.
of course tho, this should be done only if you have a decent understanding of electricity, and it should not be attempted by someone who lacks those competences, hence why hardware stores “gatekeep” male to male plugs. If you really need one and are sure you understand how they work, you can probably make one yourself.