In a vacuum c=nu*lamba or the speed of light is equal to the frequency times wavelength. So nu=c/lamba. If you plot 1/x, you don’t get a straight inverse line. You get a multiplicative inverse. So not only is the data flipped, but it also has a distortion that will compress portions and stretch others.
As to why the functions peak at different colors, I believe this is due to an oddity in the axis units. Notice how the irradiance is in W/m^2/nm in the first and W/m^2/THz in the second. Are you familiar with histograms? Think of it like binning the power intensity per nm bin and power intensity per THz bin. Since THz and nm are inversely related, the width of the bins is changing when the basis is changed. This leads to another stretching in the data that is less intuitive.